A new approach to phosphorylation of nucleosides using oxyonium phosphobetaines as intermediates

Magdalena Materna; Jacek Stawiński; MIchał Sobkowski

doi:10.5114/bta.2022.120705

eISSN: 2353-9461
ISSN: 0860-7796

BioTechnologia

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1/2023
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abstract:

SHORT COMMUNICATIONS

A new approach to phosphorylation of nucleosides using oxyonium phosphobetaines as intermediates

Magdalena Materna

¹

,

Jacek Stawiński

^{1, 2}

,

MIchał Sobkowski

¹

Institute of Bioorganic Chemistry PAS, Poznań, Poland
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden

BioTechnologia vol. 104(1) ∙ pp. 93–99 ∙ 023

DOI: https://doi.org/10.5114/bta.2022.120705

Online publish date: 2023/03/27

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Oxyonium phosphobetaines are recently discovered molecules with a unique ⁻O–P–O–N⁺ bond system, which makes them useful and versatile intermediates for the synthesis of phosphates and their derivatives. In this paper, the preliminary data on the application of these compounds in nucleoside phosphorylation were presented.

keywords:

A new approach to phosphorylation of nucleosides using oxyonium phosphobetaines as intermediates

Magdalena Materna 1 , Jacek Stawiński 1, 2 , MIchał Sobkowski 1

synthesis, phosphorylation, N-oxides, nucleotides, oxyonium phosphobetaines, H-phosphonates

Magdalena Materna

¹

,

Jacek Stawiński

^{1, 2}

,

MIchał Sobkowski

¹